Nitroxide-mediated controlled free-radical emulsion polymerization of styrene and n-butyl acrylate with a water-soluble alkoxyamine as initiator.
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Acrylates↗
Biomedical subjects
Olivier Guerret
Publications and source records attributed to Olivier Guerret.
Alkoxyamine-mediated radical synthesis of indolinones and indolines.
Thermolysis of alpha-alkoxyamino propionanilides produces indolinones, whereas thermal reaction of N-allylaniline derivatives with various Tordo-type alkoxyamines results in formation of indolines in the radical regime. [reaction: see text]
Journal Article↗
Alkoxyamine-mediated radical cyclizations.
[reaction: see text] We present a new "conjunctive" radical cyclization process that involves the reaction of a 1,6-diene with the Tordo alkoxyamine, an agent originally developed for the radical polymerization of certain olefins through the "persistent radical effect".
Journal Article↗
Free and Supported Phosphorus Ylides as Strong Neutral Brønsted Bases.
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