Large delta H not equal to and delta S not equal to values obtained in hydrolysis of alpha-chymotrypsin or catalase with alpha-chymotrypsin.
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Biomedical subjects
Publications and source records attributed to M Suzumura.
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According to the recently published "Guidebook of Measuring Method for Environmental Atmosphere" edited by the Department of Safety and Health Labour Administration of Japan, it is recommended to determine acrylamide (AAM) in air by sampling with glass fiber filter, extracting into methanol and injecting in the FID gaschromatograph (GC). Although acrylamide particle may be measured by this method, it is questionable whether a small amount of gaseous acrylamide could be determined together. We have investigated the determination of a small amount of acrylamide monomer in air by sampling it on solid adsorbent packed in a specially designed sampling tube. We concluded that it is capable to determine a small amount of acrylamide in air, by using the above mentioned sampling tube packed with Flusin-F (treated with phosphoric acid; 30--60 mesh) as the solid adsorbent, at the concentration range from 1.0 to 0.01 ppm (v/v), and the recovery rate of 82--83%.
The determination of small amount of chlorine in the atmosphere is carried on ordinarily by omicron-toluidine method at present. However, this method is not recommended because the issued colour is unstable and omicron-toluidine itself belongs in the first group member of the Ordinance on Prevention of Particular Chemical Hazards Substances. Authors recommend 4-nitroaniline method, reported by J. Gabbay etc., because this method is stable and more practical. Although the colour that issued from the reaction of chlorine with 4-nitroaniline is affected by the co-existence of reducing gas, e.g. SO2, H2S or organic gas, but this effect may be removed the co-existence of reducing gas, e.g. SO2, H2S or organic gas, but this effect may be removed by introducing the sample gas into the layer of H2SO4-52Cr2O7 mixture immersed in glassfiber filter for micro-analysis. In this paper, influence of pH of the issued colour, stability, stream velocity of samplegas and effect of reducing substance are discussed.
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