Biomedical subjects

M Centini

Publications and source records attributed to M Centini.

8 recordsLinked to original sources

PubMed2003

Dynamics of counterpropagating pulses in photonic crystals: enhancement and suppression of stimulated emission processes.

Using numerical methods, we study the propagation of counterpropagating pulses in finite photonic crystals. We show that linear interference and localization effects combine to either enhance or suppress stimulated emission processes, depending on the initial phase difference between the input pulses. We consider the example of second harmonic generation, where we find a maximum contrast of three orders of magnitude in nonlinear conversion efficiency as a function of the input phase difference between incident pulses. We interpret these results by viewing the photonic crystal as an open cavity, with a field-dependent, electromagnetic density of modes sensitive to initial and boundary conditions.

Journal Article↗

PubMed2002

New microencapsulated sunscreens: technology and comparative evaluation.

The aim of this work is to obtain new technologically improved microencapsulated sunscreens characterised by UV-radiation stability, good substantivity, low toxicity, a better tolerability and easiness to formulation. For this purpose we prepared two different systems using semisynthetic Hyaluronic Acid (HA) benzyl ester and a synthetic polymer (patent pending). We obtained these systems using two different methodologies: emulsification/solvent evaporation and emulsification/solvent extraction. The comparison between the two formulated systems was carried out in terms of their chemical-physical and biological properties.

Capsules↗

PubMed2001

Simultaneously phase-matched enhanced second and third harmonic generation.

Second and third harmonic generation via a chi((2)) three-wave mixing process can occur with high conversion efficiency in a one-dimensional photonic band gap structure. We find that it is possible to simultaneously achieve enhancement and exact phase-matching conditions of second harmonic and sum frequency generation, omega+2 omega-->3 omega. It is also remarkable that high conversion efficiencies persist under tuning conditions that correspond to a phase mismatch. While these conditions are quite unusual and cannot be achieved in any known bulk material, we show that they can be easily obtained in finite layered structures by using and balancing an interplay between material dispersion and the geometrical dispersion introduced by the structure.

Journal Article↗

PubMed2001

Photonic band edge effects in finite structures and applications to chi 2 interactions.

Using the concept of an effective medium, we derive coupled mode equations for nonlinear quadratic interactions in photonic band gap structures of finite length. The resulting equations reveal the essential roles played by the density of modes and effective phase matching conditions necessary for the strong enhancement of the nonlinear response. Our predictions find confirmation in an experimental demonstration of significant enhancement of second harmonic generation near the photonic band edge. The measured conversion efficiency is in good agreement with the conversion efficiency predicted by the effective-medium model.

Journal Article↗

PubMed2001

Group velocity, energy velocity, and superluminal propagation in finite photonic band-gap structures.

We have analyzed the notions of group velocity V(g) and energy velocity V(E) for light pulses propagating inside one-dimensional photonic band gap structures of finite length. We find that the two velocities are related through the transmission coefficient t as V(E)=/t/(2)V(g). It follows that V(E)=V(g) only when the transmittance is unity (/t/(2)=1). This is due to the effective dispersive properties of finite layered structures, and it allows us to better understand a wide range of phenomena, such as superluminal pulse propagation. In fact, placing the requirement that the energy velocity should remain subluminal leads directly to the condition V(g)<or=c//t/(2). This condition places a large upper limit on the allowed group velocity of the tunneling pulse at frequencies of vanishingly small transmission.

Journal Article↗

PubMed2000

Unsaturated hydrocarbons with fruity and floral odors.

Hydrocarbons usually do not exhibit odors of interest or well-defined character. However, certain cyclic alkenes have been associated with typical and pleasant notes, such as fruity, green, and floral. One of the best known examples is represented by the isomeric megastigmatrienes, endowed with a pleasant smell of tropical fruits. From the structures of these odorants, 24 analogues and homologues, most of them cyclic alkenes, but including also some open-chain alkenes, have been synthesized to define structural parameters related to the characteristic odors of these compounds. The number and position of double bonds, the substitution on the ring, and the size of the ring are the variables taken into account. Most of the new compounds present a mainly fruity character, associated in several cases with floral and green notes, producing an overall sensation described as "tropical fruit".

Fruit↗

PubMed1999

Dispersive properties of finite, one-dimensional photonic band gap structures: applications to nonlinear quadratic interactions.

We discuss the linear dispersive properties of finite one-dimensional photonic band-gap structures. We introduce the concept of a complex effective index for structures of finite length, derived from a generalized dispersion equation that identically satisfies the Kramers-Kronig relations. We then address the conditions necessary for optimal, phase-matched, resonant second harmonic generation. The combination of enhanced density of modes, field localization, and exact phase matching near the band edge conspire to yield conversion efficiencies orders of magnitude higher than quasi-phase-matched structures of similar lengths. We also discuss an unusual and interesting effect: counterpropagating waves can simultaneously travel with different phase velocities, pointing to the existence of two dispersion relations for structures of finite length.

Journal Article↗

PubMed1998

High-performance liquid chromatography determination of direct and temporary dyes in natural hair colourings.

A simple and reliable HPLC method is described for the simultaneous determination of nine direct and temporary hair dyes in hair colourings containing vegetal extracts. Detection was performed by a diode array detector and two different wavelengths, in the visible range (450 and 650 nm), were used for quantitation. The method does not involve any extraction procedure and it is sufficiently rapid and accurate for routine analyses. The method described was successfully applied to the identification of synthetic organic dyes in 13 direct and temporary hair dyeing formulations commercialized as 'natural'.

Chromatography, High Pressure Liquid↗