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Biomedical subjects

G van der Laan

Publications and source records attributed to G van der Laan.

At least 19 recordsLinked to original sources
PubMed2006

Angle-dependent x-ray magnetic circular dichroism from (Ga,Mn)As: anisotropy and identification of hybridized states.

Remarkably anisotropic Mn L2,3 x-ray magnetic circular dichroism spectra from the ferromagnetic semiconductor (Ga,Mn)As are reported. States with cubic and uniaxial symmetry are distinguished by careful analysis of the angle dependence of the spectra. The multiplet structures with cubic symmetry are qualitatively reproduced by calculations for an atomiclike d5 configuration in tetrahedral environment, and show zero anisotropy in the orbital and spin moments within the experimental uncertainty. However, hybridization with the host valence bands is reflected by the presence of a preedge feature with a uniaxial anisotropy and a marked dependence on the hole density.

Journal Article↗
PubMed2005

Femtosecond dynamics in ferromagnetic metals investigated with soft x-ray resonant emission.

We present measurements of the magnetic circular dichroism in x-ray resonant emission in the perpendicular geometry (circularly polarized x rays at normal incidence to the magnetization) for L(2,3) the absorption region in Fe, Co, and Ni metal. The results show that spin-dependent screening of the core hole takes place within the scattering time scale, which is supported by the absence of the effect in ionic systems. This allows an assessment of the time scale for the screening process (up to a few femtoseconds). The process is almost complete within the scattering time for Fe and Co, but this is not the case for the narrow band metal Ni which shows a much slower dynamics.

Journal Article↗
PubMed2005

Probing the population of the spin-orbit split levels in the actinide 5f states.

Spin-orbit interaction in the 5f states is believed to strongly influence exotic behaviors observed in actinide metals and compounds. Understanding these interactions and how they relate to the actinide series is of considerable importance. To address this issue, the branching ratio of the white-line peaks of the N4,5 edge for the light actinide metals, alpha-Th, alpha-U, and alpha-Pu were recorded using electron energy-loss spectroscopy (EELS) in a transmission electron microscope (TEM) and synchrotron-radiation-based X-ray absorption spectroscopy (XAS). Using the spin-orbit sum rule and the branching ratios from both experimental spectra and many-electron atomic spectral calculations, accurate values of the spin-orbit interaction, and thus the relative occupation of the j = 5/2 and 7/2 levels, are determined for the actinide 5f states. Results show that the spin-orbit sum rule works very well with both EELS and XAS spectra, needing little or no correction. This is important, since the high spatial resolution of a TEM can be used to overcome the problems of single-crystal growth often encountered with actinide metals, allowing acquisition of EELS spectra, and subsequent spin-orbit analysis, from nm-sized regions. The relative occupation numbers obtained by our method have been compared with recent theoretical results and they show a good agreement in their trend.

Actinoid Series Elements↗
PubMed2004

Hysteresis effect in FePd magnetic stripes studied by coherent soft X-ray resonant magnetic scattering.

An FePd thin film sample, showing magnetic stripe domains as imaged by magnetic force microscopy, has been measured by soft X-ray resonant magnetic scattering in reflection geometry. Illumination with coherent radiation, produced by inserting a 20 microm pinhole in front of the sample, leads to a magnetic speckle pattern in the scattered intensity that gives access to the domain morphology. Application of an in-plane magnetic field for a few seconds gives a strong change in the observed intensity fluctuations, which indicates a large degree of variation between the two patterns taken before and after field exposure. From the speckle pattern we calculate a degree of coherence of beta = 0.5 for the incident beam.

Anisotropy↗
PubMed2004

Applicability of the spin-orbit sum rule for the actinide 5f states.

The branching ratio of core-valence transitions in electron energy-loss spectroscopy and x-ray absorption spectroscopy is linearly related to the expectation value of the spin-orbit operator of the valence states. Here, we analyze the branching ratio of the N(4,5) edges in the actinides and find that the spin-orbit sum rule gives an accurate result without the need to include the core-valence interactions. The branching ratio is not only useful to study the variations in the 5f spin-orbit interaction, it also allows us to constrain the 5f count for given angular-momentum coupling conditions.

Journal Article↗
PubMed2004

Direct observation of a bulklike spin moment at the Fe/GaAs(100)-4x6 interface.

We have used x-ray magnetic circular dichroism, which offers a unique capability to give element specific information at submonolayer sensitivity, to determine the spin and orbital magnetic moments at the Fe/GaAs(100) interface. The wedge samples, grown by molecular beam epitaxy at room temperature, consisted of 0.25-1 monolayer (ML) Fe on GaAs(100)-4x6 capped with 9 ML Co and have shown Fe spin moments of (1.84-1.96)micro(B) and a large orbital enhancement. Our results demonstrate unambiguously that the Fe/GaAs(100)-4x6 interface is ferromagnetic with a bulklike spin moment, which is highly promising for spintronics applications.

Journal Article↗
PubMed2004

Soft X-ray resonant magnetic scattering from a Ni layer with modulated magnetic anisotropy.

Soft X-ray resonant magnetic scattering studies on a magnetically modulated, but nominally chemically homogenous, 5 nm Ni layer in a Cu/Ni/Cu/Co/NiO/GaAs(110) system are reported. It was possible to estimate the main chemical structure of the sample on the basis of the results from specular reflectivity and rocking scans, probing the scattering vector components in the perpendicular and in-plane direction to the Ni wires, respectively. The magnetic scattering using polarized X-rays demonstrates the magnetic modulation of the Ni layer.

Journal Article↗
PubMed2004

Unraveling orbital ordering in La0.5Sr1.5MnO4.

Orbital ordering (OO) in the layered perovskite La0.5Sr1.5MnO4 has been investigated using the enhanced sensitivity of soft x-ray resonant diffraction at the Mn L edges. The energy dependence of an OO diffraction peak over the L(2,3) edges is compared to ligand-field calculations allowing a distinction between the influences of Jahn-Teller distortions and spin correlations. The energy dependence of the diffraction peak at the Mn L1 edge is remarkably different from that observed at the Mn K edge.

Journal Article↗
PubMed2003

A gas microstrip detector for XAS studies in the photon energy region 300-1500 eV.

The ability to perform X-ray absorption spectroscopy (XAS) in the 300-1500 eV energy range allows measurements to be made on transition metal compounds. This paper describes a detector and the technique used to perform fluorescent measurements on such materials. A variety of test sample results are shown to illustrate the low energy and energy-resolving capabilities of the detector (based on gas microstrip technology). Two possible applications are also demonstrated. The first shows how the detector can be used to gather X-ray absorption spectra for the L edges of transition metals and K edges of light elements (C, O and N). The other shows how the magnetic immunity of the detector can be exploited to study the magnetic properties of materials.

Absorptiometry, Photon↗
PubMed2003

Sum rules in x-ray resonant Raman scattering: recovering the Co ground state information in CoFe2O4 as a test case.

We present an approach to x-ray resonant Raman scattering suitable for sum-rule analysis. In magnetic systems it gives ground state information as represented by an expansion in coupled multipoles of orbital and spin moments. The experiment is based on the angular dependence of the integrated peak intensities. In 3d transition elements one obtains information up to order 4 from the channel 2p(6)3d(n)-->2p(5)3d(n+1)-->2p(6)3s(1)3d(n+1). By combining these results with L(2,3) absorption dichroism, we show quantitatively the atomiclike properties of cobalt in CoFe2O4 up to high-order multipoles.

Journal Article↗
PubMed2001

Non-reciprocal X-ray linear dichroism.

Recently, a new optical effect was observed by Goulon, Rogalev, Goulon-Ginet, Benayoun, Paolasini, Brouder, Malgrange & Metcalf [Phys. Rev. Lett. (2000), 85, 4385-4388] using linearly polarized synchrotron radiation. The authors have correctly analysed the effect using the mathematical framework of Buckingham and Barron. A brief review is given with the underlying simplicity discussed from a symmetry point of view.

Letter↗
PubMed2001

[Solvent-induced chronic encephalopathy; the 'solvent team' project].

Long-term exposure to organic solvents can result in damage of the central nervous system. The WHO recognises the following stages: organic affective syndrome, mild chronic toxic encephalopathy (CTE), and severe CTE. There is no golden standard for the diagnosis of CTE. Mild CTE is characterised by fatigue, mood disturbances, memory and attention disorders. In the Netherlands, a so-called 'solvent team' consisting of an occupational physician, a neurologist, a neuropsychologist and an occupational hygienist, assesses patients suspected of having CTE. The diagnostic procedure consists of three steps: (a) interview and blood tests, (b) the computer-based Neurobehavioral Evaluation System, and (c) assessment of an exposure index, neuropsychological investigation, and clinical neurological examination. In the period 1997-1999 approximately 250 patients were assessed yearly in the Netherlands; resulting in 50 diagnoses of mild CTE a year. The real incidence is most likely higher at present, but will decline due to diminished exposure to organic solvents.

Chronic Disease↗
PubMed2001

Routine diagnostic procedures for chronic encephalopathy induced by solvents: survey of experts.

OBJECTIVES: To study the routine diagnostic procedures used in different countries for chronic toxic encephalopathy (CTE) induced by solvents. METHODS: By means of a postal questionnaire selected international experts were asked about the methods they use to diagnose patients suspected of having CTE induced by solvents, the number of patients, entrance criteria, and the results of these diagnostic procedures. RESULTS: 18 Experts working in 18 diagnostic centres responded. Most of them agreed that a diagnostic procedure for CTE induced by solvents should contain an interview and neurological, physical, and neuropsychological examinations. However, the tests used were very different, as were the classifications for CTE. Depending on the institute, a diagnosis of CTE was made in 6%--70% of the referred patients. The proportion of patients with CTE stage I ranged from 0% to 33%, stage II from 5% to 100%, and stage III from 0% to 95%. CONCLUSION: The intentions of the two 1985 conferences that aimed at clarity and uniformity of diagnosis of CTE induced by solvents are far from reached. It is possible, now the conditions are more favourable, to aim at this important goal and recommend some refinement of the then proposed criteria.

Brain Damage, Chronic↗
PubMed2000

Magnetization profile of ultrathin FePd films.

The method of circular dichroism in X-ray resonant magnetic scattering is presented which allows a straightforward determination of the magnetization profile of magnetic patterns in ultrathin films. Application to single crystalline FePd layers shows unambiguously the presence of magnetic flux closure domains whose thickness can constitute a significant fraction ( approximately 25%) of the total film.

Journal Article↗
PubMed1999

Sum rule practice.

Explore the source record for details and available documents.

Journal Article↗
PubMed1999

Parkinsonism, pyramidal signs, polyneuropathy, and cognitive decline after long-term occupational solvent exposure.

It is well known that exposure to manganese, solvents, or carbon monoxide in an occupational setting may lead to central nervous system damage and parkinsonism. The most important solvents in this respect are methanol, toluene, carbon disulfide, and n-hexane. We describe three patients who had been exposed to various solvents for more than 20 years (25, 34, and 46 years). They presented with parkinsonism, pyramidal signs, mild cognitive decline, and unresponsiveness to levodopa. Two patients had a predominantly axonal and sensory polyneuropathy of the lower legs with fasciculations in one of them. Parkinsonian features were progressive, even after the patients had stopped work. We present clinical data, neuropsychological findings, and results of brain computed tomography or magnetic resonance imaging, electroneuromyography, evoked potentials, single photon emission computed tomography, and positron-emission tomography. There is growing evidence that various organic solvents give rise to a parkinsonism syndrome with pyramidal features in susceptible individuals.

Aged↗