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Biomedical subjects

G Ruocco

Publications and source records attributed to G Ruocco.

At least 19 recordsLinked to original sources
PubMed2006

Evidence for a crossover in the frequency dependence of the acoustic attenuation in vitreous silica.

We report measurements of the sound attenuation coefficient in vitreous silica, for sound waves of wavelength between 50 and 80 nm, performed with the new inelastic UV light scattering technique. These data indicate that in silica glass a crossover between a temperature-dependent (at low frequency) and a temperature-independent (at high frequency) acoustic attenuation mechanism occurs at Q approximately equal to 0.15 nm(-1). The absence of any signature in the static structure factor at this Q value suggests that the observed crossover should be associated with local elastic constant fluctuations.

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PubMed2006

High-frequency dynamics in metallic glasses.

Using inelastic x-ray scattering we studied the collective dynamics of the glassy alloy Ni33Zr67 in the first pseudo-Brillouin-zone, an energy-momentum region still unexplored in metallic glasses. We determine key properties such as the momentum transfer dependence of the sound velocity and of the acoustic damping, discussing the results in the general context of recently proposed pictures for acoustic dynamics in glasses. Specifically, we demonstrate the existence in this strong glass of well defined (in the Ioffe-Regel sense) acoustic-like excitations well above the boson peak energy.

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PubMed2006

Multipoint holographic optical velocimetry in microfluidic systems.

We show how holographic optical trapping can be used for the multipoint measurement of fluid flow in microscopic geometries. An array of microprobes can be simultaneously trapped and used to map out the fluid flow in a microfluidic device. The optical traps are alternately turned on and off such that the probe particles are displaced by the flow of the surrounding fluid and then retrapped. The particles' displacements are monitored by digital video microscopy and directly converted into velocity field values. This technique enables the measurement of a two-dimensional flow field at points arbitrarily distributed in a three-dimensional volume. The validity of the technique is demonstrated for the case of the flow around a spinning sphere and the flow at the outlet of a microchannel.

Journal Article↗
PubMed2006

Glassy behavior of light.

We study the nonlinear dynamics of a multimode random laser using the methods of statistical physics of disordered systems. A replica-symmetry breaking phase transition is predicted as a function of the pump intensity. We thus show that light propagating in a random nonlinear medium displays glassy behavior; i.e., the photon gas has a multitude of metastable states and a nonvanishing complexity, corresponding to mode-locking processes in random lasers. The present work reveals the existence of new physical phenomena, and demonstrates how nonlinear optics and random lasers can be a benchmark for the modern theory of complex systems and glasses.

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PubMed2006

More on the phase diagram of Laponite.

The phase diagram of a charged colloidal system (Laponite) has been investigated by dynamic light scattering in a previously unexplored range of salt and clay concentrations. Specifically, the clay weight and salt molar concentrations have been varied in the ranges C(w) = 0.004 divided by 0.025 and C(s) = (1 x 10(-3) divided by 5 x 10(-3)) M, respectively. As in the case of free salt water samples (C(s) approximately = 1 x 10(-4) M), an aging dynamics toward two different arrested phases is found in the whole examined C(w) and C(s) range. Moreover a transition between these two different regimes is found. It is clear from these measurements that a revision of the phase diagram is necessary and a new "transition" line between two different arrested states is drawn.

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PubMed2005

Relationship between phase transitions and topological changes in one-dimensional models.

We address the question of the quantitative relationship between thermodynamic phase transitions and topological changes in the potential energy manifold analyzing two classes of one dimensional models, the Burkhardt solid-on-solid model and the Peyrard-Bishop model for DNA thermal denaturation, both in the confining and nonconfining version. These models, apparently, do not fit [M. Kastner, Phys. Rev. Lett. 93, 150601 (2004)] in the general idea that the phase transition is signaled by a topological discontinuity. We show that in both models the phase transition energy v(c) is actually noncoincident with, and always higher than, the energy v(theta) at which a topological change appears. However, applying a procedure already successfully employed in other cases as the mean field phi4 model, i.e., introducing a map M:v-->v(s) from levels of the energy hypersurface V to the level of the stationary points "visited" at temperature T, we find that M (v(c))=v(theta). This result enhances the relevance of the underlying stationary points in determining the thermodynamics of a system, and extends the validity of the topological approach to the study of phase transition to the elusive one-dimensional systems considered here.

Biophysics↗
PubMed2005

Relaxation dynamics in (HF)x(H2O)1-x solutions.

The high-frequency dynamics of (HF)(x)(H(2)O)(1-x) solutions has been investigated by inelastic x-ray scattering. The measurements have been performed as a function of the concentration in the range x = 0.20-0.73 at fixed temperature T = 283 K. The results have been compared with similar data in pure water (x = 0) and pure hydrogen fluoride (x = 1). A viscoelastic analysis of the data highlights the presence of a relaxation process characterized by a relaxation time and a strength directly related to the presence of a hydrogen-bond network in the system. The comparison with the data on water and hydrogen fluoride shows that the structural relaxation time continuously decreases at increasing concentration of hydrogen fluoride passing from the value for water to the one for hydrogen fluoride tau(alphaHF), which is three times smaller. This is the consequence of a gradual decreasing number of constraints of the hydrogen-bond networks in passing from one liquid to the other.

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PubMed2005

Hard-sphere-like dynamics in a non-hard-sphere liquid.

The collective dynamics of liquid gallium close to the melting point has been studied using inelastic x-ray scattering to probe length scales smaller than the size of the first coordination shell. Although the structural properties of this partially covalent liquid strongly deviate from a simple hard-sphere model, the dynamics, as reflected in the quasielastic scattering, are beautifully described within the framework of the extended heat mode approximation of Enskog's kinetic theory, analytically derived for a hard-sphere system. The present work demonstrates, therefore, the applicability of Enskog's theory beyond simple liquids.

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PubMed2005

Generalized fluctuation relation and effective temperatures in a driven fluid.

By numerical simulation of a Lennard-Jones-like liquid driven by a velocity gradient gamma we test the fluctuation relation (FR) below the (numerical) glass transition temperature T(g) . We show that, in this region, the FR deserves to be generalized introducing a numerical factor X (T, gamma) <1 that defines an "effective temperature" T(FR) =T/X . On the same system we also measure the effective temperature T(eff) , as defined from the generalized fluctuation-dissipation relation, and find a qualitative agreement between the two different nonequilibrium temperatures.

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PubMed2005

Aging under shear: structural relaxation of a non-Newtonian fluid.

The influence of an applied shear field on the dynamics of an aging colloidal suspension has been investigated by the dynamic light-scattering determination of the density autocorrelation function. Though a stationary state is never observed, the slow dynamics crosses between two different nonequilibrium regimes as soon as the structural relaxation time tau(s) approaches the inverse shear rate gamma (-1) . In the shear-dominated regime (at high gamma values) the structural relaxation time is found to be strongly sensitive to the shear rate ( tau(s) approximately gamma (-alpha) , with alpha approximately 1 ) while aging proceeds at a very slow rate. The effect of the shear on the detailed shape of the density autocorrelation function is quantitatively described, assuming that the structural relaxation process arises from the heterogeneous superposition of many relaxing units, each one independently coupled to shear with a parallel composition rule for time scales: 1/tau-->1/tau+A gamma .

Journal Article↗
PubMed2005

High-frequency longitudinal and transverse dynamics in water.

High-resolution, inelastic x-ray scattering measurements of the dynamic structure factor S (Q,omega) of liquid water have been performed for wave vectors Q between 4 and 30 nm(-1) in distinctly different thermodynamic conditions ( T=263-420 K ; at, or close to, ambient pressure and at P=2 kbar ). In agreement with previous inelastic x-ray and neutron studies, the presence of two inelastic contributions (one dispersing with Q and the other almost nondispersive) is confirmed. The study of their temperature and Q dependence provides strong support for a dynamics of liquid water controlled by the structural relaxation process. A viscoelastic analysis of the Q -dispersing mode, associated with the longitudinal dynamics, reveals that the sound velocity undergoes a complete transition from the adiabatic sound velocity ( c(0) ) (viscous limit) to the infinite-frequency sound velocity ( c(infinity) ) (elastic limit). On decreasing Q , as the transition regime is approached from the elastic side, we observe a decrease of the intensity of the second, weakly dispersing feature, which completely disappears when the viscous regime is reached. These findings unambiguously identify the second excitation to be a signature of the transverse dynamics with a longitudinal symmetry component, which becomes visible in S (Q,omega) as soon as the purely viscous regime is left.

Journal Article↗
PubMed2005

Sexuality in aging male.

A high percentage of men aged 60 or older have satisfactory sexual activity, even if reduced sexual desire, frequency of intercourses and erections, impaired satisfaction with sex and difficulty with orgasm, and decreased semen volume frequently occur. The present report analyses the following issues: erectile dysfunction, fertility, the role of hormones in influencing libido and erection mechanisms, and the therapeutic strategies suggested.

Aged↗
PubMed2004

Routes to gelation in a clay suspension.

The gelation of water suspension of a synthetic clay (Laponite) has been studied by dynamic light scattering in a wide range of clay weight concentration (C(w)=0.003-0.031). At variance with previous determination, indicating a stable liquid phase for C(w)<C(*)(w) approximately 0.015-0.018, we find that gelation actually takes place in the whole examined C(w) range. We find also that C(*)(w) marks the transition between two different routes to gelation. We hypothesize that at low concentration Laponite suspension behaves as an attractive colloid and that the slowing down of the dynamics is attained by the formation of larger and larger clusters while at high concentration the basic units of the arrested phase could be the Debye Huckel spheres associated with single Laponite plates.

Aluminum Silicates↗
PubMed2004

Topological properties of the mean-field phi4 model.

We study the thermodynamics and the properties of the stationary points (saddles and minima) of the potential energy for a phi4 mean-field model. We compare the critical energy vc [i.e., the potential energy vT evaluated at the phase transition temperature Tc ] with the energy vtheta at which the saddle energy distribution show a discontinuity in its derivative. We find that, in this model, vc >> vtheta, at variance to what has been found in different mean-field and short ranged systems, where the thermodynamic phase transitions take place at vc=vtheta [Phys. Rep. 337, 237 (2000)]]. By direct calculation of the energy vs T of the "inherent saddles," i.e., the saddles visited by the equilibrated system at temperature T , we find that vsTc approximately vtheta. Thus, we argue that the thermodynamic phase transition is related to a change in the properties of the inherent saddles rather than to a change of the topology of the potential energy surface at T= Tc. Finally, we discuss the approximation involved in our analysis and the generality of our method.

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PubMed2004

Structural relaxation in liquid water by inelastic UV scattering.

Using the novel synchrotron radiation based inelastic ultraviolet scattering technique, the dynamic structure factor of normal and supercooled liquid water has been measured at a momentum transfer Q approximately equal to 0.1 nm(-1), in the temperature range 260-340 K. The structural (alpha) relaxation has been observed in the supercooled temperature region (T< or =273 K), where the inverse relaxation time matches the frequency of the probed sound modes. The T dependence of the relaxation time shows a diverging behavior with a critical temperature T approximately equal to 220 K. These results provide a unique experimental opportunity to frame the dynamics of water in the mode-coupling theory.

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PubMed2004

Landscapes and fragilities.

The concept of fragility provides a possibility to rank different supercooled liquids on the basis of the temperature dependence of dynamic and/or thermodynamic quantities. We recall here the definitions of kinetic and thermodynamic fragility proposed in the last years and discuss their interrelations. At the same time we analyze some recently introduced models for the statistical properties of the potential energy landscape. Building on the Adam-Gibbs relation, which connects structural relaxation times to configurational entropy, we analyze the relation between statistical properties of the landscape and fragility. We call attention to the fact that the knowledge of number, energy depth, and shape of the basins of the potential energy landscape may not be sufficient for predicting fragility. Finally, we discuss two different possibilities for generating strong behavior.

Journal Article↗
PubMed2004

Fragility in p-spin models.

We investigate the relation between fragility and phase space properties - such as the distribution of states - in the mean-field p -spin model, a solvable model that has been frequently used in studies of the glass transition. By direct computation of all the relevant quantities, we find that (i) the recently observed correlation between fragility and vibrational properties at low temperature is present in this model and (ii) the total number of states is a decreasing function of fragility, at variance with what is currently believed. We explain these findings by taking into account the contribution to fragility coming from the transition paths between different states. Finally, we propose a geometric picture of the phase space that explains the correlation between properties of the transition paths, distribution of states, and their vibrational properties. However, our analysis may not apply to strong systems where inflection points in the configurational entropy as a function of the temperature are found.

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