Biomedical subjects

C Riekel

Publications and source records attributed to C Riekel.

24 records · Page 2Linked to original sources

PubMed1997

Investigation of the variation in orientation and crystallinity in poly(ethylene terephthalate) containers using microfocus X-ray diffraction.

The microfocus X-ray beamline at the European Synchrotron Radiation Facility has been used to investigate the variation in molecular orientation and crystallinity in the wall of a container fabricated from poly(ethylene terephthalate). Two-dimensional wide-angle X-ray scattering patterns were recorded and displayed in real time as the specimen was tracked across the incident X-ray beam enabling the measurement of textural changes to be made with a spatial resolution of ~2 mum.

Journal Article↗

PubMed1996

Low-angle synchrotron radiation diffraction with glass-capillary optics.

The use of borosilicate-glass-capillary optics at a chosen wavelength for low scattering has been explored using an undulator beam at the ESRF. With a 2.3 mum beam at 0.092 nm wavelength, a silver behenate powder sample was scanned in two dimensions with a 2 mum step width. Scattering from single crystallites with d(001) = 5.83 nm could be observed. The limit for observation, at low angles, was ca s approximately 0.1 nm(-1) (s = 1/d for d approximately 10 nm).

Journal Article↗

PubMed1995

Microfocus X-ray Diffraction of Spherulites of Poly-3-hydroxybutyrate.

The microfocus X-ray beamline at the European Synchrotron Radiation Facility has been used to investigate the variation in molecular orientation and crystallinity in spherulites of the organic polymer poly-3-hydroxybutyrate (PHB). This is the first report of the correlation of optical and X-ray measurements on spherulitic polymer films where X-ray diffraction patterns have been recorded and displayed continuously in real time while the specimen was tracked in steps of 10 mum across an incident X-ray beam with a diameter as small as 10 mum.

Journal Article↗

PubMed1995

A Double Multilayer Monochromator at an ESRF Undulator for Microbeam Experiments.

A water-cooled double W/Si-multilayer monochromator has been operated at an ESRF low-beta undulator beam. For a fixed distance of the two multilayers the first-order Bragg reflection was at ~8 keV. The peak power density of the beam at the exit of the multilayers was ~1 W mm(-2) and the flux density of the first order after a 10 mum collimator was 4 x 10(5) photons s(-1) mum(-2) mA(-1.) The performance of the beam in microbeam diffraction has been tested on a 20 mum W wire. The observed pseudo-Laue pattern is discussed with respect to the multilayer spectrum.

Journal Article↗

PubMedDate not supplied

Aspects of X-ray diffraction on single spider fibers.

Diffraction patterns of silk from several spider species have been obtained by synchrotron radiation using a beam size > or = 10 microm. Single fiber diffraction patterns were obtained for fiber diameters down to a few microns. Diffraction patterns recorded with a 10 microm wide X-ray beam displayed fiber texture. The presence of two fractions of different crystallinity was confirmed for a single Nephila clavipes fiber. The orientation distribution of the polymer chains of the crystalline fraction along the fiber axis was found to be about 23 degrees full-width at half maximum (fwhm). The azimuthal spread of the short-range order fraction was about 86 degrees fwhm.

Animals↗

PubMedDate not supplied

Structural processes during starch granule hydration by synchrotron radiation microdiffraction.

Starch granule hydration has been examined on the level of a single potato starch granule by static and dynamic synchrotron radiation (SR) microdiffraction techniques. A cryofrozen, hydrated granule was mapped through a 5 microm SR-beam in order to investigate its internal organization. The edge of the granule showed fiber texture scattering due to radially oriented amylopectin helices. The variation of fiber texture across the granule center supports the model of concentric shells. The crystalline phase appears, however, to increase strongly toward the granule center due to a random amylopectin fraction, which could be related to crystallization of short-range ordered amylopectin during hydration. During gelatinization, the shell structure breaks down and remaining fiber-textured amylopectin domains belong probably to the swollen starch granule envelope. Hydration of a granule was initiated by a microdrop generator and followed in situ by SR-microdiffraction. A fast hydration process with a half time of about 7 s seems to reflect the porous nature of starch granules. The size of the hydrated domains suggests that this process is limited to the level of amylopectin side chain clusters. Longer hydration times are assumed to involve remaining short-range ordered amylopectin and results in larger domains.

Kinetics↗