First-Order Wetting Transitions under Gravity.
We discuss the effect of a gravitational field on the first-order wetting transition of a liquid layer on a horizontal surface. Gravity limits the thickness of the wetting layer and leads to a smooth first-order transition line Deltaµw(T, g) in the wetting phase diagram of chemical potential difference from bulk coexistence, Deltaµ identical with µ - µc, temperature T, and gravitational acceleration g. Consequences for the interpretation of wetting experiments are pointed out. Copyright 1999 Academic Press.
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