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C Boragno

Publications and source records attributed to C Boragno.

13 recordsLinked to original sources

Friction laws for lubricated nanocontacts.

We have used friction force microscopy to probe friction laws for nanoasperities sliding on atomically flat substrates under controlled atmosphere and liquid environment, respectively. A power law relates friction force and normal load in dry air, whereas a linear relationship, i.e., Amontons' law, is observed for junctions fully immersed in model lubricants, namely, octamethylciclotetrasiloxane and squalane. Lubricated contacts display a remarkable friction reduction, with liquid and substrate specific friction coefficients. Comparison with molecular dynamics simulations suggests that load-bearing boundary layers at junction entrance cause the appearance of Amontons' law and impart atomic-scale character to the sliding process; continuum friction models are on the contrary of limited predictive power when applied to lubrication effects. An attempt is done to define general working conditions leading to the manifestation of nanoscale lubricity due to adsorbed boundary layers.

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Structural depinning of Ne monolayers on Pb at T < 6/5 K.

We have studied the nanofriction of Ne monolayers with a quartz-crystal microbalance technique at temperatures below 6.5 K and in ultrahigh-vacuum conditions. Very homogeneous and smooth lead electrodes have been physically deposited on a quartz blank at 150 K and then annealed at room temperatures. With such a Pb-plated quartz-crystal microbalance, we have observed a pronounced depinning transition separating a low-coverage region, where the film is nearly locked to the oscillating electrode, from a high-coverage region characterized by slippage at the solid-fluid boundary. Such a behavior has been found to be very reproducible. These data are suggestive of a structural depinning of the solid Ne film when it becomes incommensurate with the lead substrate, in agreement with the results of an extensive molecular-dynamics study.

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Self-organized formation of rhomboidal nanopyramids on fcc(110) metal surfaces.

We report on the far from equilibrium self-organized morphologies obtained after Xe ion irradiation of the Rh(110) and Cu(110) surfaces. Here we experimentally identify by means of high resolution LEED a novel interfacial state characterized by a rhomboidal pyramid islanding with majority steps oriented along nonequilibrium low-symmetry directions. The formation of the novel rhomboidal pyramid state and the transition to the well-known rippled phases results from a delicate interplay of kinetic processes which are controlled by acting on temperature, ion flux, and impact energy.

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Experimental investigation of the contact mechanics of rough fractal surfaces.

The nonstationary character of roughness is a widely recognized property of surface morphology and suggests modeling several solid surfaces by fractal geometry. In the field of contact mechanics, this demands novel investigations attempting to clarify the role of multiscale roughness during physical contact. Here we review the results we recently obtained in the characterization of the contact mechanics of fractal surfaces by depth-sensing indentation. One class of experiments was conducted on organic thin films, load-displacement curves being acquired by atomic force microscopy using custom-designed tips. Another class of experiments focused on well-defined crystalline and mechanically polished ceramic substrates probed by a traditional nanoindenter. We observed the first-loading cycle to be considerably affected by surface roughness. Plastic failure was found to dominate incipient contact while contact stiffness increased on decreasing fractal dimension and roughness. Our findings suggest fractal parameters to drive contact mechanics whenever the penetration depth is kept below the interface width.

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Uniaxial magnetic anisotropy in nanostructured Co/Cu(001): from surface ripples to nanowires.

We have investigated the correlation between morphology and magnetic anisotropy in nanostructured Co films on Cu(001). The formation of nanoscale ripples by ion erosion is found to deeply affect the magnetic properties of the Co film. A surface-type uniaxial magnetic anisotropy with easy axis parallel to the ripples is observed. The origin of the magnetic anisotropy has been identified with the modification of thermodynamic-step distribution induced by ripple formation. At higher ion doses, when Co ripples detach and crystalline nanowires form, a strong enhancement of the magnetic anisotropy due to magnetostatic contributions is observed.

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Nanocrystal formation and faceting instability in Al(110) homoepitaxy: true upward adatom diffusion at step edges and island corners.

Using atomic force microscopy and spot-profile analyzing low energy electron diffraction, we have observed the existence of a striking faceting instability in Al(110) homoepitaxy, characterized by the formation of nanocrystals with well-defined facets. These hut-shaped nanocrystals are over tenfold higher than the total film coverage, and coexist in a bimodal growth mode with much shallower and more populous surface mounds. We further use density functional theory calculations to elucidate the microscopic origin of the faceting instability, induced by surprisingly low activation barriers for adatom ascent at step edges and island corners.

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Is ion sputtering always a "negative homoepitaxial deposition"?

We present a scanning tunneling microscopy study of the direct comparison between homoepitaxial deposition and surface ion sputtering on the Ag(001) system. At a temperature of 200 K, sputtering results in mound formation similar to the epitaxy case, while at higher temperatures an erosive regime sets in with the appearance of regular square pits. Contrary to the conventional wisdom, which considers ion sputtering as a deposition of vacancies, the analysis of single ion impact events reveals that the process produces both adatom and vacancy clusters. The key parameter determining the temperature dependence of surface morphology turns out to be the mobility of the adatom clusters which exceeds that of vacancy clusters.

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Ripple rotation in multilayer homoepitaxy

We have investigated the homoepitaxial growth of Ag(110) in the multilayer regime. After deposition of 30 monolayers of Ag at a temperature of 210 K a ripplelike surface instability is produced and the ridges of the ripples, as well as the majority steps, are found to be parallel to <11;0> which is the thermodynamically favored orientation. As the deposition temperature is decreased to 130 K, an unexpected 90 degrees switch of the ripple orientation is observed. The ridges of the ripples and the steps are in this case parallel to <100>. In the intermediate temperature range a checkerboard of rectangular mounds results. We interpret our results in terms of the peculiar hierarchy of interlayer and intralayer diffusion barriers present on the anisotropic Ag(110) surface.

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